Question

 Why are gasoline vapors more flammable than liquid gasoline?

Answer Oxygen is required for gasoline to burn. There is far more oxygen in gasoline vapor than in liquid gasoline. This is why the flame is on top of a puddle of gas. Just the vapor is burning.
http://wiki.answers.com/Q/Why_are_gasoline_vapors_more_flammable_than_liquid_gasoline

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